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Organically-Templated Zinc and Thorium Sulfates with Chain and Layered Structures by J. N. Behera; C. N. R. Rao is a Chemistry article available to read on EtoBox.

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## Abstract Amine‐templated zinc sulfates of the formulae, [Zn(SO~4~)(H~2~O)~2~(C~10~N~2~H~8~)] (I) and [C~3~N~2~H~12~][Zn(SO~4~)] (II) both with linear structures have been prepared under hydro/solvothermal conditions. Of these, I has the chain structure formed by ZnO~4~N~2~octahedra and SO~4~ tetrahedra, while II comprises ladders formed by corner‐sharing four‐membered rings. Amine‐templated thorium sulfates of the formula [HN(CH~2~)~6~NH]~2~[Th~2~(SO~4~)~6~(H~2~O)~2~]·2H~2~O, (III) and [H~2~N(CH~2~)~4~NH~2~][Th~3~(SO~4~)~7~(H~2~O)~4~]·5H~2~O (IV) are also obtained under hydrothermal conditions. III has a sheet structure consisting of cages whereas IV has a two‐dimensional structure derived from the connectivity of ladders.

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Author

J. N. Behera; C. N. R. Rao

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)

Published

2005

Language

EN

Field

Chemistry (Physical Sciences)