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Bis(dialkylaminophosphino)ferrocenes: Reactivity and electrochemistry by Ashley R. Seibert; William G. Dougherty; W. Scott Kassel; Chip Nataro is a Chemistry article available to read on EtoBox.

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New compounds containing the 1,1 0 -bis(dialkylaminophosphino)ferrocene ligands 1,1 0 -bis(dimethylaminophosphino)ferrocene (dmapf) and 1,1 0 -bis(diethylaminophosphino)ferrocene (deapf) were prepared and characterized by NMR. The oxidative electrochemistries of these compounds were examined in methylene chloride. The transition metal compounds M n Cl 2 (P-P) (M = Pd or Pt, n = 1, P-P = dmapf or deapf; M = Au, n = 2, P-P = dmapf) displayed one-electron, Nernstian waves. The corresponding selenides were prepared and the oxidative electrochemistries, along with those of the previously prepared 1,1 0 -bis(alkylaminophosphine sulfide)ferrocene, were examined. The sulfides displayed one-electron, Nernstian oxidations. The selenides displayed electrochemically irreversible two-electron waves. The X-ray structures of the sulfides and selenides as well as that of the transition metal compounds [(AuCl) 2 (dmapf)] and [PtCl 2 (dmapf)] were determined.

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Author

Ashley R. Seibert; William G. Dougherty; W. Scott Kassel; Chip Nataro

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)

Published

2010

Language

EN

Field

Chemistry (Physical Sciences)