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Solubility of CO2 in dialkylimidazolium dialkylphosphate ionic liquids by Jelliarko Palgunadi; Je Eun Kang; Dinh Quan Nguyen; Jin Hyung Kim; Byoung Koun Min; Sang Deuk Lee; Honggon Kim; Hoon Sik Kim is a Materials Science article available to read on EtoBox.
What is Solubility of CO2 in dialkylimidazolium dialkylphosphate ionic liquids about?
The solubility of carbon dioxide in room temperature ionic liquids (RTILs), dialkylimidazolium dialkylphosphates, was measured at 313-333 K and at pressures close to atmospheric pressure, from which Henry's law coefficients, standard Gibbs free energy, enthalpy, and entropy changes of solvation were derived. The CO 2 solubility in the dialkylimidazolium dialkylphosphate was found to increase with increasing chain length of the alkyl groups on the cation and/or the anion as was similarly found in other RTILs. Among various dialkylimidazolium dialkylphosphates tested, 1-ethyl-3-methylimidazolium diethylphosphate ([EMIM][Et 2 PO 4 ]) and 1-butyl-3-methylimidazolium dibutylphosphate ([BMIM][Bu 2 PO 4 ]) exhibited the comparable or better capability of dissolving CO 2 in comparison with that of [BMIM][BF 4 ], but their absorption capacities were still lower than that of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([BMIM][Tf 2 N]).
Who reads Solubility of CO2 in dialkylimidazolium dialkylphosphate ionic liquids?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- Jelliarko Palgunadi; Je Eun Kang; Dinh Quan Nguyen; Jin Hyung Kim; Byoung Koun Min; Sang Deuk Lee; Honggon Kim; Hoon Sik Kim
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0040-6031)
- Published
- 2009
- Language
- EN
- Field
- Materials Science (Physical Sciences)