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Stepwise production of CO-rich syngas and hydrogen via methane reforming by a WO3-redox catalyst by T. Kodama; T. Shimizu; T. Satoh; K.-I. Shimizu is a Engineering article available to read on EtoBox.

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A two-step cyclic steam reforming of methane by a WO 3 /ZrO 2 redox catalyst was performed to produce CO-rich syngas and hydrogen. The two-step cyclic processes could be repeated using a redox system of WO 3 below 1273 K. The produced CO-rich syngas had the H 2 /CO ratios of about two, which was suitable for methanol production. This endothermic syngas-production process will be used as a solar thermochemical process for converting concentrated solar radiation to chemical liquid fuel of methanol in the sun-belt regions. The solar syngas-production process using the WO 3 /ZrO 2 catalyst was demonstrated in a laboratory scale under direct irradiation of the catalyst by a solar-simulated, high-flux visible light.

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Author

T. Kodama; T. Shimizu; T. Satoh; K.-I. Shimizu

Publisher

Elsevier Science; Thomas Telford; Elsevier ; Thomas Telford Ltd.; Elsevier Ltd.; ICE Publishing Ltd.; Elsevier BV (ISSN 1751-4223)

Published

2003

Language

EN

Field

Engineering (Physical Sciences)