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Can I read A Kinetic Study of the Photolysis of Ethylferrocene in Chloroform on EtoBox?
A Kinetic Study of the Photolysis of Ethylferrocene in Chloroform by Son L. Phan; Patrick E. Hoggard is a Chemistry article available to read on EtoBox.
What is A Kinetic Study of the Photolysis of Ethylferrocene in Chloroform about?
The photooxidation of ethylferrocene to ethylferricinium ion and tetrachloroferrate in CHC13 under 254 nm irradiation proceeds through light absorption by both ethylferrocene and chloroform. The products remain in solution at concentrations below 10 3 M. The fraction occurring through a solvent-initiated pathway increases during the course of the reaction. A secondary thermal reaction is responsible for generating tetrachloroferrate from ethylferricinium ion. The rate of the reaction increases during the early stages, and the data throughout the course of the reaction are consistent with the rate law (afs + bfR)/ (l + c[R]/[P]-ii[R]/[Cl ]), where [R] and [P] are the concentrations of ethylferrocene and ethylferricinium ion, respectively, and /s and /R are the fractions of light absorbed by the solvent and ethylferrocene, respectively.
Who reads A Kinetic Study of the Photolysis of Ethylferrocene in Chloroform?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Son L. Phan; Patrick E. Hoggard
- Publisher
- Walter de Gruyter GmbH
- Published
- 1998
- Language
- EN
- Field
- Chemistry (Physical Sciences)