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Synthesis, Structure and Spectral Properties of [Ni(TAMEN)](ClO~4~)~2~·DMF (TAMEN = N,N′‐Tetra(4‐antipyryl‐methyl)‐1,2‐diaminoethane), a Mannich Base Complex of Biological Relevance by Ramona Tudose; Elena-Maria Mosoarca; Ingo Pantenburg; Otilia Costişor; Gerd Meyer is a Chemistry article available to read on EtoBox.

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## Abstract The new mononuclear complex [Ni(TAMEN)](ClO~4~)~2~·DMF (TAMEN = N,N′‐tetra‐(4‐antipyrylmethyl)‐1,2‐diaminoethane) has been synthesized and its crystal structure was determined by single‐crystal X‐ray diffraction. It crystallizes with monoclinic symmetry, space group __P__2~1~/__c__ (no. 14) and unit cell parameters of __a__ = 10.8736(3), __b__ = 10.9560(4), __c__ = 45.820(2) Å, __β__ = 90.23(1)°, __Z__ = 4. The TAMEN molecule acts as a hexadentate ligand incorporating a 1,2‐diaminoethane bridge in the staggered conformational __gauche__ isomer. The nickel(II) ion is octahedrally coordinated with metal‐ligand distances ranging from 2.023(2) to 2.145(3) Å. Electronic and vibrational spectroscopy data agree well with the crystal structure.

Who reads Synthesis, Structure and Spectral Properties of [Ni(TAMEN)](ClO~4~)~2~·DMF (TAMEN = N,N′‐Tetra(4‐antipyryl‐methyl)‐1,2‐diaminoethane), a Mannich Base Complex of Biological Relevance?

Author

Ramona Tudose; Elena-Maria Mosoarca; Ingo Pantenburg; Otilia Costişor; Gerd Meyer

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 0372-7874)

Published

2006

Language

EN

Field

Chemistry (Physical Sciences)