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This article discusses the role of excited organic radicals in photoredox catalysis, highlighting their potential as photocatalysts despite skepticism regarding their efficacy due to rapid decay and degradation products. It analyzes various synthetic transformations, comparing theoretical excited state potentials with observed reactivity, and explores mechanisms that may allow these radicals to function effectively in catalysis. The authors emphasize the need for further mechanistic studies and suggest that
- Author
- dhy182
- Language
- EN