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Characterization of a distonic isomer C6H5C+(OH)OCH2 of methyl benzoate radical cation by associative ion–molecule reactions by Noémie Dechamps; Robert Flammang; Pascal Gerbaux; Pham-Cam Nam; Minh Tho Nguyen is a Chemistry article available to read on EtoBox.

What is Characterization of a distonic isomer C6H5C+(OH)OCH2 of methyl benzoate radical cation by associative ion–molecule reactions about?

The C 6 H 5 C + (OH)OCH 2 • radical cation, formally a distonic isomer of ionized methyl benzoate, has been prepared by dissociative ionization of neopentyl benzoate, as earlier suggested by Audier et al. [H.E. Audier, A. Milliet, G. Sozzi, S. Hammerum, Org. Mass. Spectrom. 25 (1990) 44]. Its distonic character has now been firmly established by its high reactivity towards neutral methyl isocyanide (ionized methylene transfer) producing N-methyl ketenimine ions. Other mass spectrometric experiments and ab initio quantum chemical calculations also concur with each other pointing toward the existence of a stable distonic radical cation.

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Author

Noémie Dechamps; Robert Flammang; Pascal Gerbaux; Pham-Cam Nam; Minh Tho Nguyen

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 1387-3806)

Published

2006

Language

EN

Field

Chemistry (Physical Sciences)