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Statistical, Gradient, Block and Graft Copolymers by Controlled, Living Radical Polymerizations by Krzysztof Matyjaszewski, Kelly A. Davis is a nonfiction available to read on EtoBox.

What is Statistical, Gradient, Block and Graft Copolymers by Controlled, Living Radical Polymerizations about?

The design and the realisation of well defined polymer architectures has become an important goal in macromolecular science. The prerequisite for achieving this goal is the availability of controlled polymerisation reactions. Living anionic polymerisation was the first reaction fulfilling these requirements. Cationic polymerisation only came into play when it was realised that it was possible to create an equilibrium between active and dormant species with the fraction of the dormant species being far superior to that of active ones. A corresponding principle applies to controlled radical polymerisation per formed in quite a number of modes such as nitroxide mediated polymerisation (NMP), atom transfer radical polymerisation (ATRP), reversible addition frag mentation chain transfer (RAFT) or catalytic chain transfer (CCT) reactions. All of these variants of controlled radical polymerisation lead to well defined archi tectures with the particular advantage that a much larger number of monomers are suitable and the reaction conditions are much less demanding than those of living ionic polymerisation reactions. Although in controlled radical polymerisation, termination reactions canno

Who reads Statistical, Gradient, Block and Graft Copolymers by Controlled, Living Radical Polymerizations?

Author

Krzysztof Matyjaszewski, Kelly A. Davis

Publisher

Springer Spektrum. in Springer-Verlag GmbH

Published

2002

Language

EN

ISBN

9783642077524

Category

nonfiction

Subjects

Science, Chemistry, Engineering