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Synthesis, crystal structure and spectroscopic characterization of new neutral and cationic (η6-p-cymene)–ruthenium(II) complexes with phosphine–amide ligands by Gregorio Sánchez; Joaquín García; Juan J. Ayllón; José L. Serrano; Luis García; José Pérez; Gregorio López is a Chemistry article available to read on EtoBox.
What is Synthesis, crystal structure and spectroscopic characterization of new neutral and cationic (η6-p-cymene)–ruthenium(II) complexes with phosphine–amide ligands about?
The dimeric starting material [Ru(g 6 -p-cymene)(l-Cl)Cl] 2 reacts with the phosphino-amides o-Ph in which phosphino-amides also act as rigid P,O-chelating ligands. The molecular structures of 2b-d were determined crystallographically. Amide deprotonation is achieved when complexes 2a-d were made react with 1 M aqueous solution of KOH, affording the corresponding neutral species 3a-d [RuCl(g 6 -p-cymene)(o-Ph 2 P-C 6 H 4 -CO-N-R)] in which a P,N-coordination mode is suggested.
Who reads Synthesis, crystal structure and spectroscopic characterization of new neutral and cationic (η6-p-cymene)–ruthenium(II) complexes with phosphine–amide ligands?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Gregorio Sánchez; Joaquín García; Juan J. Ayllón; José L. Serrano; Luis García; José Pérez; Gregorio López
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)
- Published
- 2007
- Language
- EN
- Field
- Chemistry (Physical Sciences)