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Mechanism of Isotope Exchange Reaction Between Methane and Deuterium by W. C. Gardiner JR.; J. M. Herrmann; W. G. Mallard; J. H. Owen is a Chemistry article available to read on EtoBox.

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The rate of CHI disappearance in a shock-heated CHI: Dz: Ar = 9.70: 9.86: 80.44 mixture was monitored by coincidence absorption of the 2948 cm-I He-Ne laser line over the shockfront temperature range of 1900-2300K. Comparison with CHr pyrolysis results by means of computer simulations suggested that atom and free radical chains are responsible for the homogeneous D/H exchange reaction on CHI. Additional simulations for the experimental conditions of previous single-pulse shock tube experiments led to the recognition of a high sensitivity of the exchange rate to trace amounts of hydrocarbon impurity and to the dissociation rate of CH,.

Who reads Mechanism of Isotope Exchange Reaction Between Methane and Deuterium?

Author

W. C. Gardiner JR.; J. M. Herrmann; W. G. Mallard; J. H. Owen

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0538-8066)

Published

1976

Language

EN

Field

Chemistry (Physical Sciences)