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Cleavage of the ether bond : X. The action of organocalcium halides on 1,3-benzoxathiole and 1,3-benzodioxole derivatives by S. Cabiddu; S. Melis; E. Marongiu; P.P. Piras; G. Podda is a Chemistry article available to read on EtoBox.

What is Cleavage of the ether bond : X. The action of organocalcium halides on 1,3-benzoxathiole and 1,3-benzodioxole derivatives about?

Some reactions of 1,3-benzoxathiole and 1,3-benzodioxole derivatives with organocalcium halides are described. GLC analysis of the reaction products of 1,3-benzoxathiole shows that ether bond cleavage mainly occurs, with -formation of substitution, elimination and reduction products; there is also a small amount of reductive cleavage of the thioether bond. Cleavage of only one ethereal bond occurs in the reactions of 1,3-benzodioxole. A probable reaction mechanism is discussed. '.

Who reads Cleavage of the ether bond : X. The action of organocalcium halides on 1,3-benzoxathiole and 1,3-benzodioxole derivatives?

Author

S. Cabiddu; S. Melis; E. Marongiu; P.P. Piras; G. Podda

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

1976

Language

EN

Field

Chemistry (Physical Sciences)