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NMR studies of anionic cadmium and mercury 1,1-dithiolate complexes by Brendan F. Abrahams; George Winter; Dainis Dakternieks is a Chemistry article available to read on EtoBox.

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Phosphorus-3 1, cadmium-l 13 and mercury-199 NMR data in dichloromethane solution indicate formation of anionic species when additional ligand S-S is adde,d to solutipns of M(S-S)2 [M = Cd, Hg; S-S-= $CO'Pr, $P(O'Pr),]. The dithiocarbamate analogue M[S2CNEt,],-is formed for M = Cd but when M = Hg, the complex Hg[S2CNEt,], is too weak a Lewis acid to add further dithiolate ligands. Variable temperature NMR experiments have been used to study the exchange processes associated with formation, in solution, of a number of novel dithiolate mixed-ligand complexes.

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Author

Brendan F. Abrahams; George Winter; Dainis Dakternieks

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)

Published

1989

Language

EN

Field

Chemistry (Physical Sciences)