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The crystal structure of La~2~Fe~25~P~12~ by B. I. Zimmer; W. Jeitschko is a Chemistry article available to read on EtoBox.
What is The crystal structure of La~2~Fe~25~P~12~ about?
## Abstract The new compound La~2~Fe~25~P~12~ was prepared by reaction of the elements in a tin flux. Its crystal structure was determined from single-crystal X-ray diffractometer data: __Pbam__, __a__ = 1475.6(4) pm, __b__ = 1814.9(4) pm, __c__ = 363.6(2) pm, __Z__ = 2, __R__ = 0.037 for 1765 unique structure factors and 120 variable parameters. The compound belongs to a large family of structures with a metal: phosphorus ratio close to 2:1. An unusual feature in the structure of La~2~Fe~25~P~12~ are strings of edge-sharing Fe~4~ tetrahedra extending along the short translation period.
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- Author
- B. I. Zimmer; W. Jeitschko
- Publisher
- Walter de Gruyter GmbH
- Published
- 1994
- Language
- EN
- Field
- Chemistry (Physical Sciences)