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XeF4 has a square planar shape due to four bonds with fluorine and two opposite lone pairs, making it non-polar, while PF4 has a trigonal pyramidal shape with a permanent dipole due to one lone pair. Butanol reacts with Tollens reagent as an aldehyde, whereas 2-methyl-propan-2-ol does not react with potassium dichromate due to being a tertiary alcohol. Butan-2-ol and Butanone can be identified by their respective absorption peaks in the IR spectrum.
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