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What is Safe Phosgenation via Photo-On-Demand about?

The article presents a novel photo-on-demand in situ phosgenation reaction that utilizes a heterogeneous solution of chloroform and aqueous NaOH to synthesize carbonate esters, polycarbonates, and N-substituted ureas safely and economically. The reaction involves the photochemical oxidation of chloroform to phosgene under UV light, allowing for efficient synthesis on a practical scale. The study highlights the reaction mechanisms and optimizations for various substrates, demonstrating the potential for vers

Author

Сергей Ковригин

Language

EN