Can I read Carbaborane-functionalised 2,2′:6′,2′′-terpyridine ligands for metallosupramolecular chemistry: Syntheses, complex formation, and the crystal and molecular structures of 4′-(ortho-carboranyl)-2,2′:6′,2′′-terpyridine and 4′-(ortho-carboranylpropoxy)-2,2′:6′,2′′-terpyridine1This paper is dedicated to Professor Ken Wade on the occasion of his 65th birthday.1 on EtoBox?

Carbaborane-functionalised 2,2′:6′,2′′-terpyridine ligands for metallosupramolecular chemistry: Syntheses, complex formation, and the crystal and molecular structures of 4′-(ortho-carboranyl)-2,2′:6′,2′′-terpyridine and 4′-(ortho-carboranylpropoxy)-2,2′:6′,2′′-terpyridine1This paper is dedicated to Professor Ken Wade on the occasion of his 65th birthday.1 by Dominique Armspach; Edwin C. Constable*; Catherine E. Housecroft; Markus Neuburger; Margareta Zehnder is a Chemistry article available to read on EtoBox.

What is Carbaborane-functionalised 2,2′:6′,2′′-terpyridine ligands for metallosupramolecular chemistry: Syntheses, complex formation, and the crystal and molecular structures of 4′-(ortho-carboranyl)-2,2′:6′,2′′-terpyridine and 4′-(ortho-carboranylpropoxy)-2,2′:6′,2′′-terpyridine1This paper is dedicated to Professor Ken Wade on the occasion of his 65th birthday.1 about?

A series of functionalised 2,2 :6 ,2 -terpyridine ligands, each with a closo-1,2-C B H R R s H or Si BuMe substituent in the 4 2 10 10 2 X Ž position, either directly or indirectly attached to the heterocyclic ring, has been prepared; two members of the series, 4 -3-ortho-. X X Y Ž . X Ž . X X Y Ž . carboranylpropoxy -2,2 :6 ,2 -terpyridine 4 and 4 -ortho-carboranyl -2,2 :6 ,2 -terpyridine 7 have been characterised by X-ray Ž . crystallography. The reaction of ligand 7 with alcohols results in the boron decapping of the closo-cage and yields a Zwitter-ionic nido-cluster-functionalised ligand. Analogous changes to the carbaborane cage have been observed in complexes in which the terpyridine Ž . t domain is coordinated to ruthenium II . However, decapping does not occur if a Si BuMe -protected carbaborane cage is incorporated 2 into the terpyridine ligands. q 1998 Elsevier Science S.A.

Who reads Carbaborane-functionalised 2,2′:6′,2′′-terpyridine ligands for metallosupramolecular chemistry: Syntheses, complex formation, and the crystal and molecular structures of 4′-(ortho-carboranyl)-2,2′:6′,2′′-terpyridine and 4′-(ortho-carboranylpropoxy)-2,2′:6′,2′′-terpyridine1This paper is dedicated to Professor Ken Wade on the occasion of his 65th birthday.1?

Author

Dominique Armspach; Edwin C. Constable*; Catherine E. Housecroft; Markus Neuburger; Margareta Zehnder

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

1998

Language

EN

Field

Chemistry (Physical Sciences)