Can I read CF3-torsional potentials of 2-aminobenzotrifluoride in the S0 and S1 electronic states from fluorescence spectra in a supersonic jet on EtoBox?
CF3-torsional potentials of 2-aminobenzotrifluoride in the S0 and S1 electronic states from fluorescence spectra in a supersonic jet by Robert D. Gordon; J. Michael Hollas; Paulo J.A. Ribeiro-Claro; José J.C. Teixeira-Dias is a Physics and Astronomy article available to read on EtoBox.
What is CF3-torsional potentials of 2-aminobenzotrifluoride in the S0 and S1 electronic states from fluorescence spectra in a supersonic jet about?
Both fluorescence excitation and dispersed fluorescence spectra of 2-aminobenzotrifluoride in a supersonic jet show quite extensive vibrational structure due to the CF,-torsional motion in the S, and So electronic states, respectively. This structure has been assigned and results in CF,-torsional potentials with parameters I',=450 cm-', V6=83 cm-' in S, and I',=240 cm-', V,= -67 cm-' in S,. There is some evidence which points to interaction between an amino-hydrogen atom and the fluorine atoms: this may bc due to hydrogen bonding or steric effects, or both.
Who reads CF3-torsional potentials of 2-aminobenzotrifluoride in the S0 and S1 electronic states from fluorescence spectra in a supersonic jet?
It is typically read by researchers, students, and practitioners in Physics and Astronomy.
- Author
- Robert D. Gordon; J. Michael Hollas; Paulo J.A. Ribeiro-Claro; José J.C. Teixeira-Dias
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)
- Published
- 1993
- Language
- EN
- Field
- Physics and Astronomy (Physical Sciences)