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Submillimeter-wave spectroscopy of HN2+ and DN2+ in the excited vibrational states by T. Amano; T. Hirao; J. Takano is a Chemistry article available to read on EtoBox.
What is Submillimeter-wave spectroscopy of HN2+ and DN2+ in the excited vibrational states about?
The pure rotational transitions of HN 2 + and DN 2 + in the first excited vibrational states for all the fundamental vibrational modes have been observed in the range of 300-750 GHz. The molecular constants determined are much more accurate compared with those obtained from the infrared spectroscopy. The equilibrium rotational constants, B e = 46832.45 (71) MHz for HN 2 + and B e = 38708.38 (58) MHz for DN 2 + , have been determined by correcting for the higher-order vibration-rotation interaction effects, c ij , obtained by an infrared investigation. The equilibrium bond lengths are derived from these equilibrium rotational constants: r e (H-N) = 1.03460 (14) A ̊and r e (N-N) = 1.092698 (26) A ̊.
Who reads Submillimeter-wave spectroscopy of HN2+ and DN2+ in the excited vibrational states?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- T. Amano; T. Hirao; J. Takano
- Publisher
- Elsevier Science; Elsevier ; Elsevier Inc.; Elsevier BV (ISSN 0022-2852)
- Published
- 2005
- Language
- EN
- Field
- Chemistry (Physical Sciences)