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Can I read Copper(II) and iron(III) complexes of N-nitroso-N- alkylhydroxylamines, and the X-ray crystal structures of bis(N-nitroso-N-isopropylhydroxylaminato)copper(II) and tris(N-nitroso-N-propylhydroxylaminato)iron(III) on EtoBox?
Copper(II) and iron(III) complexes of N-nitroso-N- alkylhydroxylamines, and the X-ray crystal structures of bis(N-nitroso-N-isopropylhydroxylaminato)copper(II) and tris(N-nitroso-N-propylhydroxylaminato)iron(III) by Michael H. Abraham; Joseph I. Bullock; John H.N. Garland; Andrew J. Golder; Grahame J. Harden; Leslie F. Larkworthy; David C. Povey; Michael J. Riedl; Gallienus W. Smith is a Chemistry article available to read on EtoBox.
What is Copper(II) and iron(III) complexes of N-nitroso-N- alkylhydroxylamines, and the X-ray crystal structures of bis(N-nitroso-N-isopropylhydroxylaminato)copper(II) and tris(N-nitroso-N-propylhydroxylaminato)iron(III) about?
N-nitroso-N-alkylhydroxylamines have been prepared by hydrolysis of the mixture obtained by reaction of nitric oxide with Grignard reagents, and stabilized as their copper(I1) or iron(II1) complexes, Cu(RN,O,), and Fe(RN202)3, where R is, for example, Me, Et, Pri, Bu'"", Ph, r&H' 7 or n-C12H2,. The complexes have been characterized by analytical, magnetic and spectroscopic measurements. By single-crystal X-ray methods Cu(PriN202)2 has been found to be trans-planar and Fe(PfN202), has a facial octahedral structure ; in each complex the N-G bond lengths are equal with no significant variation between the copper and iron complexes.
Who reads Copper(II) and iron(III) complexes of N-nitroso-N- alkylhydroxylamines, and the X-ray crystal structures of bis(N-nitroso-N-isopropylhydroxylaminato)copper(II) and tris(N-nitroso-N-propylhydroxylaminato)iron(III)?
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- Author
- Michael H. Abraham; Joseph I. Bullock; John H.N. Garland; Andrew J. Golder; Grahame J. Harden; Leslie F. Larkworthy; David C. Povey; Michael J. Riedl; Gallienus W. Smith
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0277-5387)
- Published
- 1987
- Language
- EN
- Field
- Chemistry (Physical Sciences)