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Organophosphite Antioxidants in Mulch Films Are Important Sources of Organophosphate Pollutants in Farmlands by Xinying Gong; Wenjun Zhang; Shuyi Zhang; Yu Wang; Xinyi Zhang; Yuan Lu; Hongwen Sun; Lei Wang is a Environmental Science article available to read on EtoBox.

What is Organophosphite Antioxidants in Mulch Films Are Important Sources of Organophosphate Pollutants in Farmlands about?

Organophosphite antioxidants (OPAs) are important auxiliary antioxidants used in plastic polymers and can be oxidized to organophosphate esters (OPEs) during production and processing. In this work, the occurrence of OPAs and OPEs in farmlands with or without mulch film applications was investigated. Six OPAs and five OPEs were detected, with the median concentrations of 2.66 ng/g (∑OPAs) and 100 ng/g (∑OPEs) in the film-mulching soil and 1.16 ng/g (∑OPAs) and 47.9 ng/g (∑OPEs) in the nonfilm-mulching soil, respectively. The oxidative derivative of AO168 (tris (2,4-di--butylphenyl) phosphite), a typical OPA, AO168═O (tris (2,4-di--butylphenyl) phosphate) was frequently detected in farmlands at the concentrations of 0-731 ng/g, which is much higher than that of the commercial OPEs (0-12.1 ng/g). This suggests that the oxidation derivatives of OPAs (OPAs═O) might be important OPE contaminants in soils. Mulch films could be their important source. According to the simulation migration experiment, the emission risk ranges of AO168 and AO168═O from mulch films to soils in China were estimated to be 3.96-87.6 and 10.5-95.3 tons/year, respectively, which were much higher than those of OPE

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Author
Xinying Gong; Wenjun Zhang; Shuyi Zhang; Yu Wang; Xinyi Zhang; Yuan Lu; Hongwen Sun; Lei Wang
Publisher
American Chemical Society (ACS)
Published
2021
Language
EN
Field
Environmental Science (Physical Sciences)

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