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Can I read Degradation and Regeneration of the Cross‐linking Agent Azo‐ T ‐Butane on EtoBox?
Degradation and Regeneration of the Cross‐linking Agent Azo‐ T ‐Butane by Timothy J. Shaw; Brian A. Jones is a Engineering article available to read on EtoBox.
What is Degradation and Regeneration of the Cross‐linking Agent Azo‐ T ‐Butane about?
## Abstract The ability of commercially available azo‐__t__‐butun (ATB) to facilitate immobilization of polysiloxane stationary phases in capillary columns deteriorates upon storage. Aged ATB produces columns with high bleed, solute retention shifts, erratic immobilization efficiency, and high activity. This deterioration is accelerated in the presence of light, suggesting free radical processes are involved. The loss of certain lowlevel impurities, which act as free radical transfer agents or radical sinks, may be responsible for the performance change. Regeneration can often temporarily be accomplished using platinum catalyzed reduction with trichlorosilane. The addition of small amounts of toluene or other radical transfer agents to aged ATB moderates the cross‐linking process, allowing the reproducible production of columns with good immobilization efficiency, excellent intertness, low thermal bleed, and proper polarity.
Who reads Degradation and Regeneration of the Cross‐linking Agent Azo‐ T ‐Butane?
It is typically read by researchers, students, and practitioners in Engineering.
- Author
- Timothy J. Shaw; Brian A. Jones
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 1040-7685)
- Published
- 1992
- Language
- EN
- Field
- Engineering (Physical Sciences)