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Electron Spin Resonance and Structure of the Radical Cation of 3-Methylpentane by Kazumi Toriyama; Keichi Nunome; Machio Iwasaki is a Physics and Astronomy article available to read on EtoBox.

What is Electron Spin Resonance and Structure of the Radical Cation of 3-Methylpentane about?

TheESR spectrum of the radical cation of 3-methylpentane (3-MP) in CFC12CF2Cl has been obtained. The spectrum is almost identical to that for the 2-methylbutane radical cation. From the spectral analysis it is concluded that 3-MP+ has a GT skeletal conformation and the unpaired electron is confined to the C&., bond giving rise to large hypertine couplings for the trans C-H, protons attached to the C2, Cs and C6 atoms, where C6 is on the side of the 3-methyl carbon atom. The results are totally consistent with concepts previously established from studies on the methyl-substituted propane and butane radical cations.

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Author

Kazumi Toriyama; Keichi Nunome; Machio Iwasaki

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)

Published

1986

Language

EN

Field

Physics and Astronomy (Physical Sciences)