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Interconversion between square-planar palladium(II) and octahedral palladium(IV) centres in a sulfur-bridged trinuclear structure by Masahiro Kouno; Naoto Kuwamura; Takumi Konno is a Chemistry article available to read on EtoBox.

What is Interconversion between square-planar palladium(II) and octahedral palladium(IV) centres in a sulfur-bridged trinuclear structure about?

Treatment of fac-[Rh(apt)] (apt = 3-aminopropanethiolate) with Pd gives an S-bridged trinuclear complex, [Pd{Rh(apt)}] ([1]), which is interconvertible with [Pd{Rh(apt)}] ([2]). This interconversion is accompanied by a drastic change between the Pd centre with an S octahedral geometry in [1] and the Pd centre with an S square-planar geometry in [2].

Who reads Interconversion between square-planar palladium(II) and octahedral palladium(IV) centres in a sulfur-bridged trinuclear structure?

Author

Masahiro Kouno; Naoto Kuwamura; Takumi Konno

Publisher

Royal Society of Chemistry (RSC)

Published

2021

Language

EN

Field

Chemistry (Physical Sciences)