Can I read Enantioselective cyanoformylation of aldehydes mediated by BINOLAM–AlCl as a monometallic bifunctional catalyst on EtoBox?

Enantioselective cyanoformylation of aldehydes mediated by BINOLAM–AlCl as a monometallic bifunctional catalyst by Jesús Casas; Alejandro Baeza; José M. Sansano; Carmen Nájera; José M. Saá is a Chemistry article available to read on EtoBox.

What is Enantioselective cyanoformylation of aldehydes mediated by BINOLAM–AlCl as a monometallic bifunctional catalyst about?

BINOLAM-AlCl's, binaphthoxide aluminium chloride species generated in situ from either (R)-or (S)-3,3%-bis(diethylaminomethyl)-2,2%-dihydroxy-1,1%-binaphthalene (BINOLAM) behave as Lewis acid-Lewis base (LA-LB) catalysts in the enantioselective addition of methyl cyanoformate to aldehydes at room temperature, thereby leading to the asymmetric synthesis of (S)-or (R)-O-methoxycarbonyl cyanohydrins, respectively.

Who reads Enantioselective cyanoformylation of aldehydes mediated by BINOLAM–AlCl as a monometallic bifunctional catalyst?

Author

Jesús Casas; Alejandro Baeza; José M. Sansano; Carmen Nájera; José M. Saá

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0957-4166)

Published

2003

Language

EN

Field

Chemistry (Physical Sciences)