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Thermochemistry of pentacarbonyl(2-propenyl) manganese and tetracarbonyl(η3-2-propenyl) manganese. Thermochemical considerations in alkenyl isomerisation reactions by Susan J. Addison; Joseph A. Connor; John A. Kincaid is a Chemistry article available to read on EtoBox.

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Microcalorimeiric measurements at elevated temperatures of the enthalpies of sublimation, thermal decomposition and iodination of [Mn(CO)s(1J1.C 3H s)] and[Mn(COli1J3\_C 3H s)] have been made to obtain the standard enthalpies of formation A. rHmO(cr) and A.rHmO(g) (in that order) as follows (values in kilojoules per mole); [Mn(CO)s(Tjl\_C 3H s)] -(727 ± 20), -(679 ±25); [Mn(COM1J3-C3Hs)] -(651 ± 12), -(570 ± 15). The values of A.rHmO(g) are used to derive enthalpy contributions for the (propenyl-Mil) bonds in these molecules. and thusto provide thermochemical information on the irreversible 1)1 -+ T]3 isornerisation reaction involved.

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Author

Susan J. Addison; Joseph A. Connor; John A. Kincaid

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

1997

Language

EN

Field

Chemistry (Physical Sciences)