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Synthesis of Sterically Crowded Derivatives of Anomeric Pairs of D-glucose Disaccharides by Sanford Mendonca; Roger A. Laine is a Biochemistry, Genetics and Molecular Biology article available to read on EtoBox.
What is Synthesis of Sterically Crowded Derivatives of Anomeric Pairs of D-glucose Disaccharides about?
Derivatization of carbohydrates is of considerable interest since the derivatives can be used for structural studies in the field of mass spectrometry. We report here the synthesis of a series of sterically crowded derivatives of various linkage and stereoisomeric glucose-glucose disaccharides with the impetus being to understand the effect of these derivatized groups on fragmentation of the glycosidic bond and the development of methodology for discernment of the anomeric configuration. The synthesis of peralkylated (methyl, ethyl, propyl, butyl, and pentyl), per-esterified (acetyl, pivaloyl, mesitoyl), and per-silylated (tert-butyl-dimethyl silyl) glucose-glucose disaccharide derivatives has been reported.
Who reads Synthesis of Sterically Crowded Derivatives of Anomeric Pairs of D-glucose Disaccharides?
It is typically read by researchers, students, and practitioners in Biochemistry, Genetics and Molecular Biology.
- Author
- Sanford Mendonca; Roger A. Laine
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0008-6215)
- Published
- 2005
- Language
- EN
- Field
- Biochemistry, Genetics and Molecular Biology (Life Sciences)