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One-Dimensional Bromo-Bridged NiIII Complexes [Ni(S,S-bn)2Br]Br2 (S,S-bn=2S,3S-diaminobutane): Synthesis, Physical Properties, and Electrostatic Carrier Doping by Shinya Takaishi; Masahiro Yamashita; Hiroyuki Matsuzaki; Hiroshi Okamoto; Hisaaki Tanaka; Shin-ichi Kuroda; Atsushi Goto; Tadashi Shimizu; Taishi Takenobu; Yoshihiro Iwasa is a Chemistry article available to read on EtoBox.

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## Abstract A new bromo‐bridged Ni^III^ compound has been synthesized. This compound displayed a strong antiferromagnetic interaction between spins located on Ni^III^ species (__J__=(2350±500) K) that result from the strong covalency of the NiBr bond and the spin‐Peierls transition below 150 K. This was shown by the results of magnetic susceptibility and ^81^Br nuclear quadrupole resonance spectroscopy analysis. We succeeded in the electrostatic carrier doping of a single crystalline sample by using a field‐effect transistor device. This compound also showed n‐type semiconductor behavior, which can be reasonably rationalized by the existence of a small amount of Ni^II^ impurities.

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Author

Shinya Takaishi; Masahiro Yamashita; Hiroyuki Matsuzaki; Hiroshi Okamoto; Hisaaki Tanaka; Shin-ichi Kuroda; Atsushi Goto; Tadashi Shimizu; Taishi Takenobu; Yoshihiro Iwasa

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 0947-6539)

Published

2008

Language

EN

Field

Chemistry (Physical Sciences)