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The Dimerization of Some Magnesacycloalkanes and Benzomagnesacycloalkenes; the Relation Between Ring Size, Ring Strain and Degree of Association by F.J.M. Freijee; G. Schat; O.S. Akkerman; F. Bickelhaupt is a Chemistry article available to read on EtoBox.

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## Magnesacycloalkanes and benzomagnesacycloalkenes have a high tendency to dimerize-To relate this tendency to the rin g size of the compounds, the degree of association i of magnesacyclohexane (I) ( monomer/dimer equilibrium) [ 11. its 2.3benzo-derivative II (monomer/dimer equilibrium). magnesacycloheptane (III) (i = 2). its 4,5-benzo-derivative IV (i = 1) and magnesacyclodecane (V) (i = 2) was determined\_ The reaction enthalpies for interaction of the compounds with proton donors were measured and the dimerization enthalpy, apparently equal to the ring strain in the monomers, was evaluated\_ The relationship between ring size. ring strain, and the degree of association is discussed-0022-328X/82/0000-0000/ooo/s02.75 0 1982 Elsevier Sequoia SA.

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Author

F.J.M. Freijee; G. Schat; O.S. Akkerman; F. Bickelhaupt

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

1982

Language

EN

Field

Chemistry (Physical Sciences)