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ChemInform Abstract: The New High-Pressure Borate Co~7~B~24~O~42~(OH)~2~·2H~2~O - Formation of Edge-Sharing BO~4~Tetrahedra in a Hydrate Borate. by Stephanie C. Neumair; Reinhard Kaindl; Hubert Huppertz is a Chemistry article available to read on EtoBox.

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Hydrate Borate. -Violet, air-and water-resistant crystals of the title compound are synthesized from a stoichiometric mixture of Co3O4 and H3BO3 (Walker-type multianvil apparatus, 6 GPa, 880 °C, 5 min). The new high--pressure phase is characterized by powder and single crystal XRD, IR, and Raman spectroscopy. The compound crystallizes in the orthorhombic space group Pbam with Z = 2. The structure is built up from corner-sharing BO4 tetrahedra forming corrugated layers, which are interconnected by two edge-sharing BO4 tetrahedra (B2O6 units) forming Z-shaped channels.

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Author

Stephanie C. Neumair; Reinhard Kaindl; Hubert Huppertz

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley (ISSN 0931-7597)

Published

2012

Language

EN

Field

Chemistry (Physical Sciences)