Can I read Synthesis, stereochemistry and decomplexation of (η-arene)(η-cyclopentadienyl) iron(II) hexafluorophosphate complexes containing amino acid side chains. A route to N-arylamino acids on EtoBox?

Synthesis, stereochemistry and decomplexation of (η-arene)(η-cyclopentadienyl) iron(II) hexafluorophosphate complexes containing amino acid side chains. A route to N-arylamino acids by Roger M.G. Roberts; Emma Johnsen is a Chemistry article available to read on EtoBox.

What is Synthesis, stereochemistry and decomplexation of (η-arene)(η-cyclopentadienyl) iron(II) hexafluorophosphate complexes containing amino acid side chains. A route to N-arylamino acids about?

q-Substituted areneXv/-cyclopentadienyl)Fe][PF 6] complexes with amino acid side chains on the arene ring have been prepared by reaction of [(~/-haloarene)(~7-cyclopentadienyl)Fe][PF 6] complexes with amino acids and amino acid esters under various conditions. Evidence is presented from I H-and 13C-NMR spectroscopy for the existence of conformational isomers resulting from re,;tricted rotation about the arene-nitrogen bond. Where a chlorine substituent is also present in the complexed arene, diastereoisomers can be ,separated by column chromatography. Decomplexation of the complexes is reported in strongly basic media or using 1,8-phenanthroline in light-catalysed reactions offering a new route to N-arylamino acids.

Who reads Synthesis, stereochemistry and decomplexation of (η-arene)(η-cyclopentadienyl) iron(II) hexafluorophosphate complexes containing amino acid side chains. A route to N-arylamino acids?

Author

Roger M.G. Roberts; Emma Johnsen

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

1997

Language

EN

Field

Chemistry (Physical Sciences)