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Asymmetric Crystallization of Bisguanidinobenzene Derivatives by Waka Nakanishi; Akiko Ogino; Masatoshi Kawahata; Kentaro Yamaguchi; Tsutomu Ishikawa is a Chemistry article available to read on EtoBox.
What is Asymmetric Crystallization of Bisguanidinobenzene Derivatives about?
We show that the mono-N-methylated and -ethylated derivatives of the achiral compound bisguanidinobenzene undergo spontaneous asymmetric crystallization into a chiral form with chiral space group P2 1 2 1 2 1 . The absolute configurations of the chiral crystals were determined by X-ray crystallography and correlated with circular dichroism (CD) spectra recorded in the solid state. The corresponding protonated and isopropylated derivatives, by contrast, afforded achiral crystals.
Who reads Asymmetric Crystallization of Bisguanidinobenzene Derivatives?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Waka Nakanishi; Akiko Ogino; Masatoshi Kawahata; Kentaro Yamaguchi; Tsutomu Ishikawa
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 2007
- Language
- EN
- Field
- Chemistry (Physical Sciences)