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## Petzow on the occasion of his 65th birthday The isothermal section of the ternary U -Rh -Pd system at 1050 °C was investigated by metallography, X-ray microanalysis and X-ray diffraction. In addition, DTA measurements were performed in the binary U -Pd system between 40 and 55 at.% U. The U -UPd, sub-system is marked by a eutectic at 995 °C and about 50 at.% U and by an intermediate phase UPd;,;,. Only the phases UPd, and UPd; were confirmed in the Pd-rich region at 1050 °C. The maximum solubility of U in Pd is 15 at.% U at this temperature. The ternary fcc Rh-Pd-Pdog5Uo 15 Solid solution range is characterized by a closed region of immiscibility which appears between 0.6 and 12 at.% U by adding U to the binary Rh-Pd solid solution. URh, and UPd, form a continuous series of an fcc solid solution. Up to 9 mole % URh; can be dissolved in the hexagonal UPd, phase. Ahexagonal U(Rh,\_,Pd,)> Laves phase (0.04 =x=0.25) was found in the ternary system whereasthis structure does not exist in the binary boundary systems. Up to 47 mole % "UzPd," can be dissolved in UzRh,. The closed region of immiscibility within the Rh-Pd-Pdo g35Uo15 Solid solution range was evaluated by use ofbinary inte

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Author

Heiko Kleykamp; Sung-Goon Kang

Publisher

Walter de Gruyter GmbH

Published

1991

Field

Engineering (Physical Sciences)