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Can I read P-Stereogenic Ir-MaxPHOX: A Step toward Privileged Catalysts for Asymmetric Hydrogenation of Nonchelating Olefins on EtoBox?
P-Stereogenic Ir-MaxPHOX: A Step toward Privileged Catalysts for Asymmetric Hydrogenation of Nonchelating Olefins by Maria Biosca; Pol de la Cruz-Sánchez; Jorge Faiges; Jèssica Margalef; Ernest Salomó; Antoni Riera; Xavier Verdaguer; Joan Ferré; Feliu Maseras; Maria Besora; Oscar Pàmies; Montserrat Diéguez is a Chemistry article available to read on EtoBox.
What is P-Stereogenic Ir-MaxPHOX: A Step toward Privileged Catalysts for Asymmetric Hydrogenation of Nonchelating Olefins about?
The Ir-MaxPHOX-type catalysts demonstrated high catalytic performance in the hydrogenation of a wide range of nonchelating olefins with different geometries, substitution patterns, and degrees of functionalization. These air-stable and readily available catalysts have been successfully applied in the asymmetric hydrogenation of di-, tri-, and tetrasubstituted olefins (ee′s up to 99%). The combination of theoretical calculations and deuterium labeling experiments led to the uncovering of the factors responsible for the enantioselectivity observed in the reaction, allowing the rationalization of the most suitable substrates for these Ircatalysts.
Who reads P-Stereogenic Ir-MaxPHOX: A Step toward Privileged Catalysts for Asymmetric Hydrogenation of Nonchelating Olefins?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Maria Biosca; Pol de la Cruz-Sánchez; Jorge Faiges; Jèssica Margalef; Ernest Salomó; Antoni Riera; Xavier Verdaguer; Joan Ferré; Feliu Maseras; Maria Besora; Oscar Pàmies; Montserrat Diéguez
- Publisher
- American Chemical Society (ACS)
- Published
- 2023
- Language
- EN
- Field
- Chemistry (Physical Sciences)