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The Phloroglucinols of Dryopteris aitoniana PICHI SERM. (Dryopteridaceae, Pteridophyta) by Josef v. Euw; Tadeus Reichstein; Carl-Johan Widén is a Chemistry article available to read on EtoBox.

What is The Phloroglucinols of Dryopteris aitoniana PICHI SERM. (Dryopteridaceae, Pteridophyta) about?

## Abstract The phenolic compounds of the fern __Dryopteris aitoniana__ were analyzed by improved methods avoiding alcaline reagents and contact with unbuffered SiO~2~, which can cause deterioration. We confirmed the presence of five of the formerly (1971) reported six compounds, while the sixth, formerly incorrectly assumed to be aspidin (based on a spot in TLC), has now been isolated as cristals (TR‐1579). It has the empirical formula C~27~H~52~O~2~, but its structure is still unknown. Five other compounds were isolated in pure form, tetra‐albaspidin BBBB (**25**‐BBBB) a known but rare phloroglucinol, and four new compounds: penta‐albaspidin BBBBB (**37**‐BBBBB), hexa‐albaspidin BBBBBB (**38**‐BBBBBB), tetraflavaspidic acid BBBB (**26**‐BBBB) and hexaflavaspidic acid BBBBBB (**39**‐BBBBBB). The structures were established by degradation NMR and partly by field‐desorption and fast‐atom‐bombardment (FAB) mass spectra. The oligoflavaspidic acids are very unstable compounds, deteriorating during isolation procedures using the older ‘standard method’.

Who reads The Phloroglucinols of Dryopteris aitoniana PICHI SERM. (Dryopteridaceae, Pteridophyta)?

Author

Josef v. Euw; Tadeus Reichstein; Carl-Johan Widén

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); Wiley-Blackwell; Wiley (ISSN 0018-019X)

Published

1985

Language

EN

ISBN

9781985068056

Field

Chemistry (Physical Sciences)