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Polymerization of 1,1,1-trifluoroacetone with aliphatic secondary amines. A proton and fluorine magnetic resonance investigation by M. M. Dhingra; K. R. Tatta is a Chemistry article available to read on EtoBox.
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## Abstract The polymerization of 1,1,1‐trifluoroacetone with aliphatic secondary amines is reported. The polymerization product is found to be a mixture of four diastereoisomers of the cyclic trimer, the structure of which has been determined using proton and fluorine magnetic resonance spectroscopy. The proportions of the isomers have been estimated to be 70:19:8:3 from the ^19^F resonance spectrum. A comparative study of the reaction products of trifluoroacetone with metallic sodium and diethylamine is also discussed.
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- Author
- M. M. Dhingra; K. R. Tatta
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; John Wiley and Sons Ltd; Wiley (ISSN 0749-1581)
- Published
- 1977
- Language
- EN
- Field
- Chemistry (Physical Sciences)