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This article discusses the kinetics of spin-forbidden chemical reactions, emphasizing the role of Transition State Theory (TST) in predicting reaction rates. It highlights the importance of the Minimum Energy Crossing Point (MECP) and spin-orbit coupling in determining reaction pathways and activation energies. The findings indicate that spin-forbidden reactions may have unfavorable activation entropies, making them less competitive than spin-allowed reactions at higher temperatures.

Author

Adhip kurian

Language

EN