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Solid-state NMR study of the kinetics of a ring chain tautomerism in a tetrahydro-1, 3-oxazine derivative by Frank G. Riddell; Martin Rogerson; Ferenc Fülöp; Gábor Bernáth is a Chemistry article available to read on EtoBox.
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## Abstract Condensation of __cis__‐__2__‐aminomethylcyclohexanol with __p__‐nitrobenzaldehyde under mild conditions initially gives the imine as the kinetically controlled product. The imine undergoes a solid‐state rearrangement to the bicyclic tetrahydro‐1, 3‐oxazine. The kinetics of the rearrangement were followed by solid‐state CP/MAS ^13^C NMR spectroscopy over the temperature range 283–297 K and the reaction was shown to have an activation energy of 85.0 ± 14.7 kJ mol^−1^. The probable reaction mechanism is discussed.
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- Author
- Frank G. Riddell; Martin Rogerson; Ferenc Fülöp; Gábor Bernáth
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; John Wiley and Sons Ltd; Wiley (ISSN 0749-1581)
- Published
- 1995
- Language
- EN
- Field
- Chemistry (Physical Sciences)