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A general method to obtain Sturmian functions for continuum and bound state problems with Coulomb interactions by A. L. Frapiccini; J. M. Randazzo; G. Gasaneo; F. D. Colavecchia is a Physics and Astronomy article available to read on EtoBox.

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## Abstract In this article, we investigate discretization schemes to represent Sturmian functions for both positive and negative energies in the presence of a long range Coulomb potential. We explore two methods to obtain Sturmian functions for positive energy. The first one involves the expansion of the radial wave function in a __L__^2^ finite basis set, whereas the second one introduces the discretization of the radial coordinate domain of the Hamiltonian or, alternatively, the Green function. We apply them to find the bound states and scattering phase shift for ${\cal N}$‐electron atoms close to the critical charge. Both methods are able to describe bound states near threshold, as well as continuum states with very good convergence properties. © 2009 Wiley Periodicals, Inc. Int J Quantum Chem, 2010

Who reads A general method to obtain Sturmian functions for continuum and bound state problems with Coulomb interactions?

Author

A. L. Frapiccini; J. M. Randazzo; G. Gasaneo; F. D. Colavecchia

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0020-7608)

Published

2009

Language

EN

Field

Physics and Astronomy (Physical Sciences)