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Copper‐Mediated Phosphorylation of Arylsilanes with H‐Phosphonate Diesters by Haiqing Luo; Kai Sun; Qi Xie; Xiaolan Li; Xiuqi Zhang; Xuzhong Luo is a Chemistry article available to read on EtoBox.
What is Copper‐Mediated Phosphorylation of Arylsilanes with H‐Phosphonate Diesters about?
Herein we report a facile method for the synthesis of arylphosphonates via copper-mediated the cross-coupling reaction in the presence of 1, 10-Phenanthroline and Ag 2 O. This method features a broad scope with respect to both the arylsilanes and H-phosphonate diesters. Mechanistically, the reaction is proposed to involve oxidation by phosphinyl radical and reductive elimination process as the two key steps. With the optimized conditions established, various arylphosphonates were obtained up to 74% yield. This protocol is the first example of copper mediated the ArÀ P bond formation of various arylsilanes with H-phosphonates, and this novel methodology expands the applications of low cost and toxicity copper reagent in ArÀ P bond construction.
Who reads Copper‐Mediated Phosphorylation of Arylsilanes with H‐Phosphonate Diesters?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Haiqing Luo; Kai Sun; Qi Xie; Xiaolan Li; Xiuqi Zhang; Xuzhong Luo
- Publisher
- Wiley (John Wiley & Sons); Wiley - VCH Verlag GmbH & Co. KG; Wiley (ISSN 2193-5807)
- Published
- 2020
- Language
- EN
- Field
- Chemistry (Physical Sciences)