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New organically templated vanadium tellurites: (H~2~pn)[V~2~TeO~8~] (pn is propane-1,3-diamine) by Xihe Huang; Zhongqian Liu; Changcang Huang; Lijuan Shen; Xiaobao Yan is a Chemistry article available to read on EtoBox.

What is New organically templated vanadium tellurites: (H~2~pn)[V~2~TeO~8~] (pn is propane-1,3-diamine) about?

The title compound, poly[propane-1,3-diaminium hexa-mu-oxido-dioxidotellurium(IV)divanadium(V)], (C3H12N2)[V2O8Te] or (H2pn)[V2TeO8] (pn is propane-1,3-diamine), contains a two-dimensional anionic layer and the diprotonated pn cation for charge compensation. The anionic layer consists of pyrovanadates and [TeO3] pyramids, which are linked alternately through corner-sharing to form a one-dimensional chain. These one-dimensional chains are crosslinked through two weak Te-O bonds, constructing an anionic layer. Hydrogen bonds are observed involving the diprotonated pn cation and the O atoms of the anionic framework.

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Author

Xihe Huang; Zhongqian Liu; Changcang Huang; Lijuan Shen; Xiaobao Yan

Publisher

International Union of Crystallography; Blackwell Publishing Inc.; International Union of Crystallography (IUCr); Wiley (ISSN 0108-2701)

Published

2009

Language

EN

Field

Chemistry (Physical Sciences)