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Molecular Compounds and their Spectra. II by Robert S. Mulliken is a Chemistry article available to read on EtoBox.
What is Molecular Compounds and their Spectra. II about?
MOLECULAR COMPOUNDS AND THEIR SPECTRA 81 1 [CONTRIBUTION FROM THE DEPARTMENT OF PHYSICS, UNIVERSITY OF CHICAGO I Molecular Compounds and their Spectra, 111 BY ROBERT S. MULLIKEN (1) A simple general quantum-mechanical theory is presented for the interaction of electron acceptors and donors (Lewis acids and bases) to form 1:l or n:l molecular compounds ranging from loose complexes to stable compounds. This puts into more accurate or more general form ideas which have been in frequent use for some time. The theory involves resonance between no-bond structures (A,B) and dativestructures (A--B+), whereA is an acceptor atom, molecule, or ion and B is a donor atom, molecule, or ion. Two classes of donors ( r , and n or onium, bases) and three classes of acceptors ( 7 , v or vacantorbital, and d or dissociative) are particularly considered; i (ionic) donors and acceptors are also mentioned. General and specific factors governing the strengths of interaction between acceptors and donors of various classes are deduced from the theory. (2) A special class of intense electronic absorption spectra characteristic of molecular compounds A.B, and non-existent for either partner A or B alone, is p
Who reads Molecular Compounds and their Spectra. II?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Robert S. Mulliken
- Published
- 1952
- Language
- EN
- Field
- Chemistry (Physical Sciences)