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Origin of Crystallization Suppression in a New Amorphous Molecular White-Light-Generating Material by Klee, Benjamin Danilo; Paulus, Benedict; Vasco, Jonathan Link; Dehnen, Stefanie; Pilgrim, Wolf-Christian; Hosokawa, Shinya; Stellhorn, Jens Rüdiger; Hayakawa, Shinjiro is a scholarly article available to read on EtoBox.

What is Origin of Crystallization Suppression in a New Amorphous Molecular White-Light-Generating Material about?

The microscopic structure of a new infrared-driven amorphous white-light-generating material was explored by X-ray diffraction, EXAFS and Reverse Monte Carlo simulation. In this material, structural disorder appears to be prerequisite for this nonlinear optical effect. The results are consistent with quantum chemical predictions, but it is also found that the molecular cores are distorted, which is identified as a crystallization inhibitor. Sulfur atoms thereby form a uniform vibrational network, which may be responsible for the high capability of the material to absorb infrared radiation.

Author

Klee, Benjamin Danilo; Paulus, Benedict; Vasco, Jonathan Link; Dehnen, Stefanie; Pilgrim, Wolf-Christian; Hosokawa, Shinya; Stellhorn, Jens Rüdiger; Hayakawa, Shinjiro

Published

2022

Language

EN