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Unsymmetrical Ni^II^–Imidoylamidine Complexes Derived from a Novel Oxime‐Mediated Single‐Pot Reaction of Nitriles by Maximilian N. Kopylovich; Matti Haukka; Alexander M. Kirillov; Vadim Yu. Kukushkin; Armando J. L. Pombeiro is a Chemistry article available to read on EtoBox.
What is Unsymmetrical Ni^II^–Imidoylamidine Complexes Derived from a Novel Oxime‐Mediated Single‐Pot Reaction of Nitriles about?
## Abstract The neutral bisimidoylamidine (or 1,3,5‐triazapentadiene) Ni^II^ complexes [Ni{H__N__C(R)NC(C~6~H~4~CO)__N__}~2~] {R=Me, Et, __n__Pr, __i__Pr, (CH~2~)~3~Cl}, bearing an iminoisoindolinone moiety, have been generated by a novel 2‐propanone oxime‐mediated single‐pot reaction of phthalonitrile and nickel(II) acetate in solution of the corresponding alkylnitrile (RCN). Single‐crystal X‐ray diffraction analyses indicate a square‐planar geometry of the imidoylamidine core. The synthesised compounds represent rare specimens of genuine unsymmetrical imidoylamidine complexes as well as their first examples generated from nitriles in a single‐pot reaction.
Who reads Unsymmetrical Ni^II^–Imidoylamidine Complexes Derived from a Novel Oxime‐Mediated Single‐Pot Reaction of Nitriles?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Maximilian N. Kopylovich; Matti Haukka; Alexander M. Kirillov; Vadim Yu. Kukushkin; Armando J. L. Pombeiro
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 0947-6539)
- Published
- 2007
- Language
- EN
- Field
- Chemistry (Physical Sciences)