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Can I read Bis{μ-2-[(2,3-dichlorophenyl)amino]benzoato-κ O }di-μ~2~-ethoxo-octamethyldi-μ~3~-oxo-tetratin(IV) on EtoBox?
Bis{μ-2-[(2,3-dichlorophenyl)amino]benzoato-κ O }di-μ~2~-ethoxo-octamethyldi-μ~3~-oxo-tetratin(IV) by Rafal Kruszynski; Tadeusz J. Bartczak is a Chemistry article available to read on EtoBox.
What is Bis{μ-2-[(2,3-dichlorophenyl)amino]benzoato-κ O }di-μ~2~-ethoxo-octamethyldi-μ~3~-oxo-tetratin(IV) about?
The title compound, [Sn 4 (CH 3 ) 8 (C 13 H 8 Cl 2 NO 2 ) 2 (C 2 H 5 O) 2 O 2 ], is a centrosymmetric dimer, with three linearly fused fourmembered SnÐOÐSnÐO rings. The coordination polyhedron of the Sn atom bonded to the carboxylate can be described as trigonal±bipyramidal distorted toward squarepyramidal. That of the second Sn atom is similar, but the distortion towards square-pyramidal geometry is greater. The SnÐO and SnÐC distances are 2.020 (2)±2.226 (2) and 2.096 (4)±2.114 (4) A Ê , respectively. The benzene rings of the 2-[(2,3-dichlorophenyl)amino]benzoate ligand subtend an angle of 50.49 (17) ; the conformation of the ligand is stabilized by intramolecular NÐHÁ Á ÁCl and NÐHÁ Á ÁO hydrogen bonds. The structure is assembled via %±% stacking interactions to form chains parallel to [120].
Who reads Bis{μ-2-[(2,3-dichlorophenyl)amino]benzoato-κ O }di-μ~2~-ethoxo-octamethyldi-μ~3~-oxo-tetratin(IV)?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Rafal Kruszynski; Tadeusz J. Bartczak
- Publisher
- International Union of Crystallography; Blackwell Publishing Inc.; International Union of Crystallography (IUCr); Wiley (ISSN 0108-2701)
- Published
- 2005
- Language
- EN
- Field
- Chemistry (Physical Sciences)