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Can I read Allylic Hydroxy Phosphonates: Versatile Chiral Building Blocks on EtoBox?
Allylic Hydroxy Phosphonates: Versatile Chiral Building Blocks by Antonette De la Cruz; Anyu He; Anchalee Thanavaro; Bingli Yan; Christopher D. Spilling; Nigam P. Rath is a Chemistry article available to read on EtoBox.
What is Allylic Hydroxy Phosphonates: Versatile Chiral Building Blocks about?
Allylic hydroxy phosphonates are converted into b and c substituted amino phosphonates using a series of palladium-catalyzed reactions. The judicious selection of nitrogen nucleophile and palladium catalyst allow for excellent regio-and stereochemical control. Palladium(0)-catalyzed amine addition or tosyl carbamate rearrangement gives rise to the c-substituted phosphonates, whereas, reaction of tosyl carbamates with palladium (II) and base gives oxazolidinones (b-substitution).
Who reads Allylic Hydroxy Phosphonates: Versatile Chiral Building Blocks?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Antonette De la Cruz; Anyu He; Anchalee Thanavaro; Bingli Yan; Christopher D. Spilling; Nigam P. Rath
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)
- Published
- 2005
- Language
- EN
- Field
- Chemistry (Physical Sciences)