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Efficient synthesis of (2R,3S)- and (2S,3S)-2-amino-1,3,4-butanetriols through stereodivergent hydroxymethylation of d-glyceraldehyde nitrones by Pedro Merino; Santiago Franco; Francisco L. Merchan; Julia Revuelta; Tomas Tejero is a Chemistry article available to read on EtoBox.
What is Efficient synthesis of (2R,3S)- and (2S,3S)-2-amino-1,3,4-butanetriols through stereodivergent hydroxymethylation of d-glyceraldehyde nitrones about?
The nucleophilic addition of two alkoxymethyllithium derivatives to three D-glyceraldehyde derived nitrones has been investigated. The diastereofacial selectivity of the reaction could be controlled by the appropriate use of Lewis acids as precomplexing agents of the nitrones. The obtained syn and anti adducts were further converted into C-4 building blocks and b-hydroxy-a-aminoacids.
Who reads Efficient synthesis of (2R,3S)- and (2S,3S)-2-amino-1,3,4-butanetriols through stereodivergent hydroxymethylation of d-glyceraldehyde nitrones?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Pedro Merino; Santiago Franco; Francisco L. Merchan; Julia Revuelta; Tomas Tejero
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 2002
- Language
- EN
- Field
- Chemistry (Physical Sciences)