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The Crystal and Molecular Structure of Bis(diethylcarbamoyl)mercury by K. Toman; G. G. Hess is a Chemistry article available to read on EtoBox.
What is The Crystal and Molecular Structure of Bis(diethylcarbamoyl)mercury about?
Abstract The crystal structure of bis(diethylcarbamoyl)mercury, [(C2H5)2NCO]2Hg, has been determined by x-ray diffraction. Due to twinning of the crystals, the analysis had to be based on reflections having h + k even, and packing considerations. The crystals are monoclinic, with cell dimensions a = 15.014(8) Å, b = 11.930(9) Å, c = 4.082(2) Å, β = 115.13(3)°. The space group is either P21/a, P21 or Pa, with two molecules per unit cell. The C–Hg bond length is 2.13(2) Å. No intermolceular coordination to the Hg atom is observed; the intermolecular distances are Hg...N, 3.67(3) Å, and Hg...O, 3.40(3) Å.
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- Author
- K. Toman; G. G. Hess
- Publisher
- Walter de Gruyter GmbH
- Published
- 1975
- Language
- EN
- Field
- Chemistry (Physical Sciences)