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Factors affecting the reproducibility and reliability of retention simulation in any form of temperature programmed capillary GC by Yafeng Guan; Linge Li; Liangmo Zhou is a Chemistry article available to read on EtoBox.

What is Factors affecting the reproducibility and reliability of retention simulation in any form of temperature programmed capillary GC about?

## Abstract Conversion of Kováts retention indices on a given stationary phase into the thermodynamic parameters of compounds on a given column leads to a simplified method for retention simulation in isothermal, linear, and multi‐ramp temperature programmed capillary gas chromatography. The influence of numerical methods used in the computation, the temperature coefficient of Kováts indices, and the experimental factors such as isothermal temperatures selected in the measurement of __n__‐alkanes, column characterization and sample overloading, on the reproducibility and accuracy of simulation were discussed and examined. When the column used is properly characterized, the error between the simulated values and the experimental data is within ± 0.5 index unit or less than ± 1% of retention time.

Who reads Factors affecting the reproducibility and reliability of retention simulation in any form of temperature programmed capillary GC?

It is typically read by researchers, students, and practitioners in Chemistry.

Author
Yafeng Guan; Linge Li; Liangmo Zhou
Publisher
John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Ltd.; Wiley (ISSN 0935-6304)
Published
1995
Language
EN
Field
Chemistry (Physical Sciences)