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Can I read Synthesis, Crystal Structure, and Photoluminescence of a Dumbbell-like Sodium Dicyanamide Compound with 15-Crown-5 on EtoBox?
Synthesis, Crystal Structure, and Photoluminescence of a Dumbbell-like Sodium Dicyanamide Compound with 15-Crown-5 by Xi Liu; Wen-Juan Ru; Zhen Zhao is a Chemistry article available to read on EtoBox.
What is Synthesis, Crystal Structure, and Photoluminescence of a Dumbbell-like Sodium Dicyanamide Compound with 15-Crown-5 about?
## Abstract Gaseous diffusion of __n__-hexane into the reaction mixture of sodium dicyanamide NaN(CN)~2~ with 15-crown-5 in tetrahydrofuran leads to a sodium dicyanamide compound [Na(15-crown-5)]N(CN)~2~ (1). Compound 1 exhibits a centrosymmetric dumbbell-like structure constructed by dicyanamide ligands double-bridging [Na(15-crown-5)]^+^ moieties with a μ-1,5 coordination mode. Solid-state photoluminescence experiments have shown that compound 1 emits violet luminescence, and its possible emission mechanism was investigated in detail based on theoretical calculations.
Who reads Synthesis, Crystal Structure, and Photoluminescence of a Dumbbell-like Sodium Dicyanamide Compound with 15-Crown-5?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Xi Liu; Wen-Juan Ru; Zhen Zhao
- Publisher
- Walter de Gruyter GmbH
- Published
- 2017
- Language
- EN
- Field
- Chemistry (Physical Sciences)